I heard that there were several experiences from US users who used PSU having evergy-saving function to limit its standby power under 1 watte about 5 min OS shut-down. as far as I know, to boot, there should be over 1 watte power on +5Vsb for some gigabyte motherboard.
So, you'd better try to boot the motherboard juster after OS shutdown wheterh it could boot then isolate your problem.