The board allows the usage of 2 sets of SATA ports ,some as IDE some as AHCI.
Using this approach you will be able to use AHCI under XP.
Install in IDE mode XP then switch the DVD ROM unit SATA port to AHCI.
Search for a driver to install for that AHCI device and when you find one that installs ,and the optical unit gets usable ,switch in BIOS to AHCI all together ,it should work,
The AHCI driver suggested by Gigabyte may not work under XP ,but the AMD RAID ones installed manually may work.