i don't want to use "both at the same time"...
That is right you can't run both at the same time. When I set my M2 drive up on a X99 board. I set it up using the Raid controller. I even disconnected all of the drives other the DVD & M2. Because I did want a dual boot.
I want to use the F12 key to choose which OS I want to boot too. Once I got windows 10 installed then I connected all the drives again. Now when it boots the M2 shows up on the Raid screen with the other drives.
What I'm trying to say to you & the OP. That when you install the windows on the M2. You didn't have it set Raid it was set to AHCI. The m2 drive is on the AHCI and the other one is on the Raid controller.
It has to be either AHCI or Raid not both. The two controllers do not work together. If you want a Raid setup then everything has to be on that controller.
Plus I haven't try this yet. You might only be able to use the UEFI DVD or UEFI USB to install it. If you are using two different OS you might not be to use the Windows 8/10 feature
Now if you are only installing windows 10 then yes set it up to the Windows 8/10 feature. Boot to the UEFI DVD or USB. With the Sata controller set to Raid.
Now over on the other thread where shadowsports is trying to do for you. Is see if you can change it from AHCI to Raid in safe mode. That is with out having to install windows again.
This is right from the book:
When installing different types of M.2 SSDs (including SATA SSDs, PCIe x4 SSDs, and PCIe x2 SSDs), be
sure to refer to the supported configurations in the tables below according to the operating mode of your
SATA controller (AHCI mode or RAID mode).