Ive had problems using 4 sticks of PSC, BDBG, and Hyper. This issue does not appear to be Gigabyte specific either. When all 4 slots are occupied on any Giga or Asus board I have, I get a reboot loop or massive instability.
FIX:
The reference and control voltages are set by a ratio of 1/2 the DIMM voltage. To get all 4 working, the ratio is NOT optimal and needs to be set to .49.
So, on Gigabyte, (using the Z68XP-UD4) I set volgate to 1.72 dimm, 0.850 for the 4 reference voltages which are the last 4 that say .750 next to them. this resolved my instability and boot issue. NOW if you want to use 1.65v or whatever voltage you want, follow the 1.72v instructions then modify the dram voltage. The bios retains the ratio you set so its all good from there. Hope this helps you, it certainly helped me (and i didnt get any help from anybody to come to this solution so it took like 2 weeks to figure it out)