Greetings,
Just FYI.. F8 or lower are the best BIOS(s) for the 4790K (devil's canyon). The Broadwell (5th gen) specific BIOS don't always work well with 4th gen CPU's. So I think you are ok with F6.
I've not used the Intel XTU. If it is still installed, try disabling all OC, delete any saved profiles and uninstall the software.
Can't say what will help, but you can try any/all of the following:
BIOS
CLR_CMOS - Load Defaults
If you are running Fast Boot, disable
In OS:
If using any utilities for OC, disable (first), then uninstall
Run SFC /scannow from elevated command prompt
Run Start Up Repair > Advanced Start Up Options
System Restore to a point in time pre-OC
Try disabling Fast Start Up and test boot
Worst case. Back up your system (full disk image)
Hardware evaluation:
Install a fresh copy of windows and see if the behavior follows
I just don't have any experience with the Intel Utility to know if it increases voltage with an OC. The 4790K will do 4400Mhz all day long. Going for 4600Mhz and /or trying to push the onboard HD4600 graphics isn't worth the trouble.