Your system has AGP, so therefore no PCI-E slots. PCI is not cross compatible with PCI-E, the only variant of PCI is PCI-X which is two PCI extended, and PCI-X is not PCI-E.
What is the rest of your system? AGP is very aged, it might be worthwhile upgrading to a new system, as you have limited options after that. Newer games with DX10 may feel unplayable. I would consider going for a new motherboard/cpu/ram/gpu upgrade, but the economic downturn may not be in your favour.