CML16GX3M2A1600C10 is a 16GB dual channel kit, not a 32GB quad channel kit.
If you are combining multiple kits, I would advise you not to use XMP (eXtreme Memory Profile) as the settings are for two not four DIMMs. I would recommend you clear the CMOS to remedy the missing size. After clearing the CMOS, first Load Optimized Defaults from the BIOS 'Save and Exit Setup' menu, then make any custom changes that you may have.
Corsair says it is definitely possible that two kits would run together in the same system, there is a chance that you may need to reduce the speed of the memory due to motherboard chipset limitations when populating more than one memory module per channel on the board. If you have problems mixing sets, it is suggested to manually lower the frequency of the memory.
I see the memory is already running at 1333MHz not 1600MHz. Do you recall buying two kits? I would try manually setting the memory clock and DRAM Timings.
I wouldn't expect two kits to work correctly together however there is a chance that they will. Do you have a link to where you bought the memory?