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You can use Macrium Reflect
http://www.macrium.com/reflectfree.aspor Drive Snapshot
http://www.drivesnapshot.de/en/If you use this, you may need to repair windows startup, twice. This is what I use.
Both programs will keep your alignment, others may or may not. Some have had success with Acronis, but if you use that be sure it's the latest and that you restore MBR and disk signature when restoring. That's how I've got it to keep alignment.
Before you go to do the single to RAID, you must enable RAID in the OS first, then in the BIOS as well. Then do the backup with RAID enabled, using a single drive in RAID Non-Member mode, then do the restore to the array.
To enable RAID in windows now, make the following registry changes, then reboot and set your BIOS to RAID and you will be good to go.
Enable switching between all IDE/AHCI/RAID modes by changing "Start" Values in these keys to 0
HKEY_LOCAL_MACHINE\System\CurrentControlSet\Services\Msahci\Start
HKEY_LOCAL_MACHINE\System\CurrentControlSet\Services\Pciide\Start
HKEY_LOCAL_MACHINE\SYSTEM\CurrentControlSet\services\iaStorV\Start
I don't think you need any other controllers, but you could add a bit of voltage to your SB just to be safe if you wanted.
Let me know if you run into any issues. I'll also copy this to your thread, in case others find it later and would like to know how to do it.
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Aligned is the start of your data on the SSD, all SSD's need to be aligned. If you let windows 7 create your partitions for you on your initial install your drive should already be aligned. You can check the alignment with AS SSD benchmark, it will show the alignment in green (Good) or red (Bad)
http://www.alex-is.de/PHP/fusion/downloads.php?cat_id=4Now that I mention that though, I think you might have a problem with single to RAID move, if you let windows setup your disks previously. I say this because of the hidden 100MB partition. Please post me an image of your AS SSD benchmark and I'll let you know for sure.
Ether way you can rebuild the BCD if there is an issue, that's what will be missing on the backup/restore as it's in the 100MB hidden partition, but you can fix that - it's just a little more work for you is all.
I am not sure what you are asking in your last 2-3 sentences?