First let me start by saying, absic you are brilliant...I am [and I'm sure many others as well] very grateful for your help. Thanks for sharing the knowledge overall.
I am indeed installing the OS onto the SSD. Ok so last night I got it all running before reading your reply. I disconnected the Blue Ray, but then was able to successfully use the blue ray after I created the RAID. I couldn't see the RAID until I installed the RAID drivers within Windows7. The RAID5 array physical drives were placed precisely on SATA_1-3, and the blue ray is on SATA3 5, I did however install the SSD onto SATA3_4.
It seems to be running fine, but do you think I will run into any issues? (eg. no 6.0Gbit/s speed)