What RAM modules are you using? EDIT: OK if I read your original post I would know that..... Doh!
on the packet it should tell you the Voltage as well as the timings for them. These are what you need to set in BIOS.
RAM will be set at the default voltage of 1.5V. If, for example, your RAM is rated to run at 1866MHz at 1.65V then you will need to set the RAM voltage to that. With your modules you shouldn't need to do this. When you go into the voltage control section of BIOS it is pretty straight forward and it will show you the available voltage settings. When you move above 1.5V you will get a red warning message flashing on the right-hand panel about over volting the system but this can be safely ignored.
Just a thought but, as you are running a 4 stick kit, you may find that the system will not BOOT properly (this has happened on the GA-990FXA-UD3) when you increase the RAM speed to 1866MHz and it only BOOTS with 2 sticks of RAM. We haven't got to the reason for this yet and it may not happen on this motherboard, but forewarned is forearmed as they say.