Some older boards have a limitation of 2 ram sticks if ram speed is set faster than 1333
It s not related to the speed ,it s related to the stick configuration or the BIOS itself.
That X6 CPU has the best IMC in Phenom 2 series CPU-s ,it takes 1600Mhz RAM just fine and the IMC overclocks to 2,4-2,6 Ghz easily.
The board though is a cheap one and BIOS could be underdeveloped regarding RAM compatibility or amount.
I would test the CPU and RAM in a different motherboard.
That CPU is a nice one and with a better board you could get some "juice" out of it