Hi, I have tried the hardware fixes before hand, just didnt mention it in my post.
I tried swapping the modules and run them individually in the first slot, both RAM sticks work.
The status screen still shows that the bios detects both modules but, the underlying issue was still the 3rd slot is not enabled.
No matter which module I set into the 3rd DIMM slot, it does not automatically enabled, only the 1st slot is enabled.
And, yes I did remove the CPU when I rebuilt my PC.
I will memtest both modules individually just to make sure.